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Zirconium(IV) sulfate : ウィキペディア英語版
Zirconium(IV) sulfate

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Zirconium(IV) sulfate is the name for a family of inorganic compounds with the formula Zr(SO4)2(H2O)n where n = 0, 4, 5, 7. These species are related by the degree of hydration. They are white or colourless solids that are soluble in water.
==Preparation and structure==
Zirconium sulfate is prepared by the action of sulfuric acid on zirconium oxide:
:ZrO2 + 2 H2SO4 + H2O → Zr(SO4)2(H2O)x
The anhydrous sulfate is also known.
These compounds adopt complex structures featuring 7- and 8-coordinated Zr centres. Both water and sulfate serve as ligands.〔Bear, Isabel J.; Mumme, W. G. "Crystal chemistry of zirconium sulfate. III. Structure of the β-pentahydrate, Zr2(SO4)4(H2O)8.2H2O, and the interrelationship of the four higher hydrates" Acta Cryst. 1969. B25, 1572-1581. 〕〔Squattrito, Philip J.; Rudolf, Philip R.; Clearfield, Abraham "Crystal structure of a complex basic zirconium sulfate" Inorganic Chemistry 1987, vol. 26, 4240-4.〕

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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